Electronic and Optical Properties of d-Band Perovskites
The perovskite family of oxides includes a vast array of insulators, metals, and semiconductors. Current intense scientific interest stems from the large number of diverse phenomena exhibited by these materials including pseudo two-dimensional electronic energy bands, high temperature superconductivity, metal-insulator transitions, piezoelectricity, magnetism, photochromic, and catalytic activity. This book is the first text devoted to a comprehensive theory of the solid-state properties of these fascinating materials. The text includes complete descriptions of the important energy bands, photoemission, surface states, and the chapter on high-temperature superconductors explores the electronic states in typical copper-oxide materials. Theoretical results are compared to experiment and discussed throughout the book. With problem sets included, this is a unified, logical treatment of fundamental perovskite solid-state chemistry which will appeal to graduate students and researchers alike.
- First book on d-band perovskites and only text that gives theory of surface states of perovskites
- Problem sets at the end of each chapter
- Uses theory common to materials scientists, chemists and physicists
Product details
October 2006Hardback
9780521850537
328 pages
253 × 180 × 21 mm
0.801kg
82 b/w illus. 29 tables 69 exercises
Available
Table of Contents
- 1. Discussion of the perovskites
- 2. N-electron systems
- 3. Empirical LCAO model
- 4. LCAO model for cubic perovskites
- 5. Bands at symmetry points
- 6. Density of states
- 7. Optical properties
- 8. Photoemission from perovskites
- 9. Surface states on perovskites
- 10. Distorted perovskites
- 11. High-temperature superconductors
- A. Physical constants
- B. The delta function
- C. Lattice Green's function
- D. Surface and bulk Madelung potentials for the ABO3 structure.